Inorganic Syntheses Nonmolecular Solids [Hardcover]

The volumes in this continuing series provide a compilation of current techniques and ideas in inorganic synthetic chemistry. Includes inorganic polymer syntheses and preparation of important inorganic solids, syntheses used in the development of pharmacologically active inorganic compounds, small-molecule coordination complexes, and related compounds. Also contains valuable information on transition organometallic compounds including species with metal-metal cluster molecules. All syntheses presented here have been tested.Chapter One BINARY COMPOUNDS.

1. Tungsten Dichloride.

2. Zirconium Monochloride and Monobromide.

3. Lanthanum Triiodide (and Other Rare-Earth Metal Triiodides).

4. Lanthanum Diiodide.

5. Rare-Earth Sesquisulfides, Ln2S3.

6. Group IV Sulfides.

7. Titanium Disulfide.

8. Metathetical Precursor Route to Molybdenum Disulfide.

9. Lithium Nitride, Li3N.

10. Aluminum Nitride.

11. Electrochemical Syntheses of Binary Silver Oxides.

12. Trisodium Heptaphosphide and Trisodium Undecaphosphide.

Chapter Two TERNARY COMPOUNDS.

13. Lead Ruthenium Oxide, Pb2[Ru2-xPb?4+x]O6.5.

14. Calcium Manganese Oxide, Ca2Mn3O8.

15. Ternary Chlorides and Bromides of the Rare-Earth Elements.

16. Cesium Scandium(II) Trichloride.

17. A One-Dimensional Polychalcogenide, K4Ti3S14.

18. Synthesis of K4M3Te17 (M = Zr, Hf) and K3CuNb2Se12.

19. Synthesis of Ternary Chalcogenides in Molten Polychalcogenide Salts: alpha-KCuQ4, KAuS5, NaBiS2, KFeQ2 (Q = S, Se).

Chapter Three CRYSTAL GROWTH.

20. Single Crystals of Transition-Metal Dioxides.lóQ