In current materials R&D, high priority is given to surface modification techniques to achieve improved surface properties for specific applications requirements. Plasma treatment and polymerization are important technologies for this purpose. This book provides a basic and thorough presentation of this subject. This is probably the first book to cover plasma treatment and polymerization for the purpose of surface modification. Chemistry, processes and applications are detailed. More than 150 figures include numerous schematics which illustrate the chemistry and processes. More than 100 tables and graphics provide useful reference data in convenient form.Introduction
Plasma Plasma State - Dissociation Energy - Energy for Ionization: Energy Transfer by Particle Collision, Energy Transfer by Photon Absorption - Cross Section of Collision - Properties of Plasma: Debye Length and Debye Shielding, Electron Temperature and Ion Temperature, Velocity Distribution Function - Plasma Generation - References Interactions between Plasma and Polymeric Materials Etching Reactions - Implantation Reactions - Radical Generation - Polymer Deposition - Polymer Deposition and Ablation - References Plasma Graft Copolymerization Radicals Created by Plasma - Plasma Graft Polymerization - Plasma Graft Polymerization and Photoinitiated Graft Polymerization - References Surface Modification by Implantation History of Implantation Process as Surface Modification - Chemistry of CASING Process - Mechanism of Implantation - Implantation by Remote Plasma - Hydrophilic Surface Modification by Implantation of Oxygen Functionalities - Hydrophilic Surface Modification by Implantation of Chlorine Functionalities - Hydrophobic Surface Modification by Implantation of Fluorine Functionalities - Implantation and Degradation - References Plasma Polymerization History of Plasma Polymerization - Plasma Polymerization Mechanism -lC7